Systematic Analysis of ARPES Spectra of Transition-Metal Oxides: Nature of Effective<i>d</i>Band

Hiroki Wadati, Akira Chikamatsu, Masaru Takizawa, Hiroshi Kumigashira, T. Yoshida, T. Mizokawa, A. Fujimori, Masaharu Oshima, Noriaki Hamada

Type: Article

Publication Date: 2009-08-28

Citations: 3

DOI: https://doi.org/10.1143/jpsj.78.094709

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Abstract

We have performed a systematic tight-binding analysis of the angle-resolved photoemission spectroscopy (ARPES) spectra of a series of transition-metal (TM) oxides A(TM)O 3 and compared the obtained electronic structure parameters with those well established values obtained from cluster-model analyses of photoemission spectra. The values of ε d -ε p from ARPES are found to be much larger than the values which would be expected for the limit of weak p – d hybridization, indicating that the “effective” TM 3 d bands are originated from the strong hybridization with the O 2 p bands even for light TM oxides.

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