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Excimer Formation in Zinc-phthalocyanine Revealed using Ultrafast Electron Diffraction

Excimer Formation in Zinc-phthalocyanine Revealed using Ultrafast Electron Diffraction

The formation of excited dimer states, so called excimers, is an important phenomenon in many organic molecular semiconductors. In contrast to Frenkel exciton-polaron excited states, an excimer is long-lived and energetically low-lying due to stabilization resulting from a substantial reorganization of the inter-molecular geometry. In this letter, we show that …