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Design monolayer iodinenes based on halogen bond and tiling theory

Design monolayer iodinenes based on halogen bond and tiling theory

Xenes, two-dimensional (2D) monolayers composed of a single element, with graphene as a typical representative, have attracted widespread attention. Most of the previous Xenes, $X$ from group-IIIA to group-VIA elements, have bonding characteristics of covalent bonds. In this paper, we unveil the pivotal role of a halogen bond, which is …