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Reactions of Acetonitrile with Trapped, Translationally Cold Acetylene Cations

Reactions of Acetonitrile with Trapped, Translationally Cold Acetylene Cations

The reaction of the acetylene cation (C2H2+) with acetonitrile (CH3CN) is measured in a linear Paul ion trap coupled to a time-of-flight mass spectrometer. C2H2+ and CH3CN are both noted for their astrochemical abundance and predicted relevance for understanding prebiotic chemistry. The observed primary products are c-C3H3+, C3H4+, and C2NH3+. …