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Out-of-time-order correlator for the van der Waals potential

Out-of-time-order correlator for the van der Waals potential

The quantum-to-classical correspondence is often quantified in dynamics by the out-of-time-order correlator (OTOC). In chaotic systems, the OTOC is expected to grow exponentially at early time, characteristic of a Lyapunov exponent; however, exponential growth can also occur for integrable systems. Here we investigate the OTOC for realistic diatomic molecular potentials …