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Integral fluctuation theorem and generalized Clausius inequality for microcanonical and pure states

Integral fluctuation theorem and generalized Clausius inequality for microcanonical and pure states

Fluctuation theorems are cornerstones of modern statistical mechanics and their standard derivations routinely rely on the crucial assumption of a canonical equilibrium state. Yet rigorous derivations of certain fluctuation theorems for microcanonical states and pure energy eigenstates in isolated quantum systems are still lacking and constitute a major challenge to …