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Prediction of single-atom-thick transition metal nitride <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>CrN</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:math> with a square-planar network and high-temperature ferromagnetism

Prediction of single-atom-thick transition metal nitride <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>CrN</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:math> with a square-planar network and high-temperature ferromagnetism

Single-atom-thick two-dimensional materials such as graphene usually have a hexagonal lattice while the square-planar lattice is uncommon in the family of two-dimensional materials. Here, we demonstrate that single-atom-thick transition metal nitride CrN$_4$ monolayer is a stable free-standing layer with a square-planar network. The stability of square-planar geometry is ascribed to …