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Gauge invariance of light-matter interactions in first-principle tight-binding models

Gauge invariance of light-matter interactions in first-principle tight-binding models

We study the different ways of introducing light-matter interaction in first-principle tight-binding (TB) models. The standard way of describing optical properties is the velocity gauge, defined by linear coupling to the vector potential. In finite systems a transformation to represent the electromagnetic radiation by the electric field instead is possible, …