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Charge, lattice and magnetism across the valence crossover in EuIr<sub>2</sub>Si<sub>2</sub> single crystals

Charge, lattice and magnetism across the valence crossover in EuIr<sub>2</sub>Si<sub>2</sub> single crystals

We present a detailed study of the temperature evolution of the crystal structure, specific heat, magnetic susceptibility and resistivity of single crystals of the paradigmatic valence-fluctuating compound [Formula: see text]. A comparison to stable-valent isostructural compounds [Formula: see text] (with Eu3+), and [Formula: see text], (with Eu2+) reveals an anomalously …