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Quasiparticle band-edge energy and band offsets of monolayer of molybdenum and tungsten chalcogenides

Quasiparticle band-edge energy and band offsets of monolayer of molybdenum and tungsten chalcogenides

We report the quasiparticle band-edge energy of monolayer of molybdenum and tungsten dichalcogenides, MX2 (M = Mo, W; X = S, Se, Te). Beyond calculating bandgaps, we have achieved converged absolute band-edge energies relative to the vacuum level. Compared with the results from other approaches, the GW calculation reveals substantially …