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Programming Substrate-Independent Kinetic Barriers With Thermodynamic Binding Networks

Programming Substrate-Independent Kinetic Barriers With Thermodynamic Binding Networks

Engineering molecular systems that exhibit complex behavior requires the design of kinetic barriers. For example, an effective catalytic pathway must have a large barrier when the catalyst is absent. While programming such energy barriers seems to require knowledge of the specific molecular substrate, we develop a novel substrate-independent approach. We …