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Spin interactions and magnetic order in the iron oxychalcogenides <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>BaFe</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>Q</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mspace width="4pt" /><mml:mo>(</mml:mo><mml:mrow><mml:mi>Q</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">S</mml:mi><mml:mspace width="4pt" /><mml:mtext>and Se</mml:mtext><mml:mo>)</mml:…

Spin interactions and magnetic order in the iron oxychalcogenides <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>BaFe</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>Q</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mspace width="4pt" /><mml:mo>(</mml:mo><mml:mrow><mml:mi>Q</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">S</mml:mi><mml:mspace width="4pt" /><mml:mtext>and Se</mml:mtext><mml:mo>)</mml:…

The ability to tune the iron chalcogenides ${\mathrm{BaFe}}_{2}{Q}_{3}$ from Mott insulators to metals and then superconductors with applied pressure has renewed interest in low-dimensional iron chalcogenides and oxychalcogenides. We report here a combined experimental and theoretical study on the iron oxychalcogenides ${\mathrm{BaFe}}_{2}{Q}_{2}\mathrm{O}\phantom{\rule{4pt}{0ex}}(Q=\mathrm{S},\text{Se})$ and show that their magnetic behavior results from …