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The process $e^+e^-\rightarrow pK^{0}_{S}\bar{n}K^{-} + c.c.$ and its intermediate processes are studied for the first time, using data samples collected with the BESIII detector at BEPCII at center-of-mass energies of 3.773, 4.008, 4.226, 4.258, 4.358, 4.416, and 4.600 GeV, with a total integrated luminosity of 7.4 fb$^{-1}$. The Born cross …