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Critical role of electronic correlations in determining crystal structure of transition metal compounds

Critical role of electronic correlations in determining crystal structure of transition metal compounds

The choice that a solid system makes when adopting a crystal structure (stable or metastable) is ultimately governed by the interactions between electrons forming chemical bonds. By analyzing 6 prototypical binary transition-metal compounds we demonstrate here that the orbitally-selective strong $d$-electron correlations influence dramatically the behavior of the energy as …