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Interplay between structure and magnetism in the low-dimensional spin system: K(C<sub>8</sub>H<sub>16</sub>O<sub>4</sub>)<sub>2</sub>CuCl<sub>3</sub>·H<sub>2</sub>O
Materials based on a crown ether complex together with magnetic ions, especially Cu(II), can be used to synthesize new low dimensional quantum spin systems. We have prepared the new crown ether complex di-μ-chloro-bis(12-crown-4)-aquadichloro-copper(II)-potassium, K(C8H16O4)2CuCl3·H2O (1), determined its structure, and analyzed its magnetic properties. Complex (1) has a monoclinic structure and …