Theory of linear sweep voltammetry with diffuse charge: Unsupported electrolytes, thin films, and leaky membranes
Theory of linear sweep voltammetry with diffuse charge: Unsupported electrolytes, thin films, and leaky membranes
Linear sweep and cyclic voltammetry techniques are important tools for electrochemists and have a variety of applications in engineering. Voltammetry has classically been treated with the Randles-Sevcik equation, which assumes an electroneutral supported electrolyte. In this paper, we provide a comprehensive mathematical theory of voltammetry in electrochemical cells with unsupported …