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Control of the Magnetism and Magnetic Anisotropy of a Single-Molecule Magnet with an Electric Field

Control of the Magnetism and Magnetic Anisotropy of a Single-Molecule Magnet with an Electric Field

Through systematic density functional calculations, the mechanism of the substrate induced spin reorientation transition in FePc/O-Cu(110) is explained in terms of charge transfer and rearrangement of Fe-3d orbitals. Moreover, we find giant magnetoelectric effects in this system, manifested by the sensitive dependence of its magnetic moment and magnetic anisotropy energy …