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Electronics and Optics of Graphene Nanoflakes: Edge Functionalization and Structural Distortions

Electronics and Optics of Graphene Nanoflakes: Edge Functionalization and Structural Distortions

The effects of edge covalent functionalization on the structural, electronic, and optical properties of elongated armchair graphene nanoflakes (AGNFs) are analyzed in detail for a wide range of terminations, within the framework of Hartreeā€“Fock-based semiempirical methods. The chemical features of the functional groups, their distribution, and the resulting system symmetry ā€¦