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<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>Cu</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi>Nb</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>8</mml:mn></mml:msub></mml:math>: A Multiferroic with Chiral Coupling to the Crystal Structure

<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>Cu</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi>Nb</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>8</mml:mn></mml:msub></mml:math>: A Multiferroic with Chiral Coupling to the Crystal Structure

By combining bulk properties, neutron diffraction, and nonresonant x-ray diffraction measurements, we demonstrate that the new multiferroic ${\mathrm{Cu}}_{3}{\mathrm{Nb}}_{2}{\mathrm{O}}_{8}$ becomes polar simultaneously with the appearance of generalized helicoidal magnetic ordering. The electrical polarization is oriented perpendicularly to the common plane of rotation of the spins---an observation that cannot be reconciled with …