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Energy and symmetry of dd excitations in undoped layered cuprates measured by Cu<i>L</i><sub>3</sub>resonant inelastic x-ray scattering

Energy and symmetry of dd excitations in undoped layered cuprates measured by Cu<i>L</i><sub>3</sub>resonant inelastic x-ray scattering

We measured high resolution Cu $L_3$ edge resonant inelastic x-ray scattering (RIXS) of the undoped cuprates La$_2$CuO$_4$, Sr$_2$CuO$_2$Cl$_2$, CaCuO$_2$ and NdBa$_2$Cu$_3$O$_6$. The dominant spectral features were assigned to $dd$ excitations and we extensively studied their polarization and scattering geometry dependence. In a pure ionic picture, we calculated the theoretical cross …