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Optical Pumping and Vibrational Cooling of Molecules

Optical Pumping and Vibrational Cooling of Molecules

The methods producing cold molecules from cold atoms tend to leave molecular ensembles with substantial residual internal energy. For instance, Cs2 molecules initially formed via photoassociation of cold Cs atoms are in several vibrational levels, v, of the electronic ground state. Here we apply a broadband femtosecond laser that redistributes …