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Role of <i>p</i>– <i>f</i> Hybridization in the Metal–Nonmetal Transition of PrRu<sub>4</sub>P<sub>12</sub>
Electronic state evolution in the metal–nonmetal transition of PrRu 4 P 12 has been studied by X-ray and polarized neutron diffraction experiments. It has been revealed that, in the low-temperature nonmetallic phase, two inequivalent crystal-field (CF) schemes of Pr 3+ 4 f 2 electrons with Γ 1 and Γ 4 …