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Precision Measurement of Transition Matrix Elements via Light Shift Cancellation

Precision Measurement of Transition Matrix Elements via Light Shift Cancellation

We present a method for accurate determination of atomic transition matrix elements at the ${10}^{\ensuremath{-}3}$ level. Measurements of the ac Stark (light) shift around ``magic-zero'' wavelengths, where the light shift vanishes, provide precise constraints on the matrix elements. We make the first measurement of the $5s\ensuremath{-}6p$ matrix elements in rubidium …