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Leaving the fullerene road: presence and stability of sp chains in sp<sup>2</sup>carbon clusters and cluster-assembled solids
We report an experimental and theoretical investigation of the growth and structure of large carbon clusters produced in a supersonic expansion by a pulsed microplasma source. The absence of a significant thermal annealing during the cluster growth causes the formation of disordered structures, where sp2 and sp hybridizations coexist for …