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Metal-Ligand Interplay in Strongly Correlated Oxides: A Parametrized Phase Diagram for Pressure-Induced Spin Transitions

Metal-Ligand Interplay in Strongly Correlated Oxides: A Parametrized Phase Diagram for Pressure-Induced Spin Transitions

We investigate the magnetic properties of archetypal transition-metal oxides MnO, FeO, CoO, and NiO under very high pressure by x-ray emission spectroscopy at the $K\ensuremath{\beta}$ line. We observe a strong modification of the magnetism in the megabar range in all the samples except NiO. The results are analyzed within a …