Type: Article
Publication Date: 2003-11-21
Citations: 40
DOI: https://doi.org/10.1103/physrevlett.91.218302
We investigate a class of reaction processes in which particles move ballistically and react upon colliding. We show that correlations between velocities of colliding particles play a crucial role in the long time behavior. In the reaction-controlled limit when particles undergo mostly elastic collisions and therefore are always near equilibrium, the correlations are accounted analytically. For ballistic aggregation, for instance, the density decays as n approximately t(-xi) with xi=2d/(d+3) in the reaction-controlled limit in d dimensions, in contrast with the well-known mean-field prediction xi=2d/(d+2).