SU\G(𝔸)/K·U

Photoionization of the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mn>3</mml:mn><mml:msup><mml:mi>s</mml:mi><mml:mn>2</mml:mn></mml:msup><mml:mn>3</mml:mn><mml:msup><mml:mi>p</mml:mi><mml:mn>4</mml:mn></mml:msup><mml:mspace width="0.16em" /><mml:mrow><mml:msup><mml:mrow /><mml:mn>3</mml:mn></mml:msup></mml:mrow><mml:mi>P</mml:mi></mml:mrow></mml:math>and the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mn>3</mml:mn><mml:msup><mml:mi>s</mml:mi…

Mathias Barthel, R. Flesch, E. Rühl, B M McLaughlin

Type: Article

Publication Date: 2015-01-20

Citations: 17

DOI: https://doi.org/10.1103/physreva.91.013406

Abstract

Photoionization of neutral atomic sulfur in the ground and metastable states was studied experimentally at a photon energy resolution of 44 meV FWHM. Relative cross section measurements were recorded by using tunable vacuum ultraviolet (VUV) radiation in the energy range 9 -- 30 eV obtained from a laser-produced plasma and the atomic species were generated by photolysis of molecular precursors. Photoionization of this atom is characterized by multiple Rydberg series of autoionizing resonances superimposed on a direct photoionization continuum. A wealth of resonance features observed in the experimental spectra are spectroscopically assigned and their energies and quantum defects tabulated. The cross-section measurements are compared with state-of-the-art theoretical cross-section calculations obtained from the Dirac Coulomb R-matrix method. Resonances series in the spectra are identified and compared indicating similar features in both the theoretical and experimental spectra.

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  • arXiv (Cornell University) - View - PDF
  • Refubium (Universitätsbibliothek der Freien Universität Berlin) - View - PDF
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